Barcelona were left stunned as Nelson Haedo Valdez struck twice to give promoted side Hercules a famous 2-0 win at the Nou Camp. Meanwhile, Jose Mourinho enjoyed a winning home debut as Real Madrid got their campaign up and running with a narrow 1-0 victory over Osasuna. Centre-back Ricardo Carvalho netted the only goal of the game just after half-time to give Madrid the spoils in a match they dominated but struggled to finish off a battling Osasuna side.
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