Barcelona host Sevilla in the mouthwatering clash of the weekend.
Leaders Real Madrid, who are three points clear at the top after only three games, will be looking to extend their winning streak to five in all competitions, when they visit promoted Valladolid on Sunday.
Bernd Schuster's side have a 100 percent record in the league and beat Werder Bremen 2-1 in their Champions League opener on Tuesday.
Third-placed Valencia, and under-fire coach Quique Sanchez Flores, visit Real Betis.
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